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Joel Madden and De Bono sang a fiery rendition of It Will Rain by Bruno Mars and Delta Goodrem and her "mini me" Rachael Leahcar serenaded the audience with The Prayer.
It was the only lackluster duet of the night, and Urban chose to stick with Martin for his "intrigue".
The show closed with the most explosive battle of the night between Mahalia Barnes and Prinnie Stevens.
The friends brought the house down with their powerful performance of Tainted Love.
KARISE Eden has been crowned the first ever Voice of Australia.
The blues singer took out the inaugural title, beating fellow finalists Darren Percival, Sarah De Bono and Rachael Leahcar.